Product ID:GENTROL IGR CONCENTRATE
MSDS Date:04/21/1995
FSC:6840
NIIN:01-318-7416
MSDS Number: CCMBG

VAN WATERS AND ROGERS INC

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3400/800-424-9300(CHEMTREC)

Info Phone: 206-889-3400

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

ETHYL

CAS: 65733-18-8

RTECS: JR1700000

PETROLEUM HYDROCARBON/MINERAL OIL,PETROLEUM

CAS: 64742-47-8

RTECS: OA5504000

OSHA PEL 5 MG/M3 (OIL MIST)

ACGIH TLV: 5 MG/M3 (OIL MIST)

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL S, 200 PPM

ACGIH TLV: S,200PPM/250STEL; 96

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS > 5,100 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- MAY CAUSE EYE IRRITATION.
REPEATED/PROLONGED SKIN CONTACT CAN CAUSE IRRITATION. HIGH VAPOR
CONCENTRATIONS MAY PRODUCE CNS EFFECTS. INGESTI ON MAY CAUSE GI
TRACT IRRITATION, VOMITING. ASPIRATION HAZARD. CONTAINS METHANOL.
MAY CAUSE BLINDNESS. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, NAUSEA,
UNCONSCIOUSNESS, COUGHING, LABORED BREATHING, SKIN DRYNESS,
DERMATITIS, TEARING, BLURRED VISION, BLINDNESS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED CNS OR RESPIRATORY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.

First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:FLUSH WITH WATER FOR 15
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO
NOT IN DUCE VOMITING. IF CONSCIOUS, RINSE MOUTH WITH WATER. SEEK
IMMEDIATE MEDICAL ATTENTION. IF SPONTANEOUS VOMITING OCCURS, KEEP
HEAD BELOW HIPS.

Flash Point Method:TCC
Flash Point:132F,56C
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL/CARBON DIOXIDE. DON'T
USE DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE
REIGNITED.
Fire Fighting Procedures:DO NOT ENTER ANY ENCLOSED OR CONFINED AREA
WITHOUT PROPER PROTECTIVE EQUIPMENT AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPOR IN PRESENCE OF AN IGNITION SOURCE
CAN IGNITE AND FLASH BACK. CONTAINERS MAY RUPTURE DUE TO VAPOR
PRESSURE BUILDUP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. PICK UP SPILL WITH NON-FLAMMABLE
ABSORBENT SUCH AS SAND OR VERMICULITE. PREVENT LIQUID FROM ENTERING
SEWERS OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA, AWAY
FROM HEAT, FLAMES, SPARKS, HOT SURFACES & INCOMPATIBLE MATERIALS.
KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:FLAMMABLE. EMPTY CONTAINERS MAY RETAIN RESIDUE.
FOLLOW ALL LABEL DIRECTIONS. KEEP OUT OF REACH OF CHILDREN. AVOID
BREATHING VAPORS. DO NOT GET IN EYE, ON SKIN OR ON CLOTHING. AVOID
DIRECT SUN. DO NOT INGEST.

Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A
NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:USE EXPLOSION-PROOF VENTILATION EQUIPMENT TO CONTROL VAPOR
CONCENTRATIONS.
Protective Gloves:NITRILE FOR REPEATED/PROLONGED CONTACT
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD
BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF
EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health

HCC:F5
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:0.85
Solubility in Water:EMULSIFIES
Appearance and Odor:STRAW COLORED LIQUID WITH MILD PETROLEUM SOLVENT
ODOR
Percent Volatiles by Volume:98

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, FLAMES, SPARKS, HOT SURFACES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SULFUR OXIDES MAY BE FORMED.

Waste Disposal Methods:DISPOSE OF IN AN APPROVED INCINERATOR OR
CONTRACT WITH LICENSED CHEMICAL WASTE DISPOSAL SERVICE. DISCHARGE,
TREATMENT OR DISPOSAL IS SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.